Please reconnect. Please reconnect. Theoretical and experimental studies of the 3-aza-Claisen rearrangement. Die Anwendung von Isotopen in der organischen Chemie. Enter your email address below and we will send you your username, If the address matches an existing account you will receive an email with instructions to retrieve your username, I have read and accept the Wiley Online Library Terms and Conditions of Use. Allyl phenyl ether is a good starting reactant for many different experiments. The wittig reaction: Stereoselectivity and a history of mechanistic ideas (1953–1995). Die Reversibilität der para-Claisen-Umlagerung. 10 publications. Nematic Solvents as Media for the Claisen Rearrangement. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Mitteilung. Claisen rearrangement of allyl phenyl ether: heavy-atom kinetic isotope effects and bond orders in the transition structure. Your Mendeley pairing has expired. Claisen Rearrangement over the Past Nine Decades. organic chemical reaction that offers a powerful method in the formation of carbon-carbon bonds Zur Kenntnis der Claisen-Umlagerung VI. This article is cited by This article is cited by Unlimited viewing of the article/chapter PDF and any associated supplements and figures. S. Kirk Wright,, Michael S. DeClue,, Ajay Mandal,, Lac Lee,, Olaf Wiest,, W. Wallace Cleland, and. These metrics are regularly updated to reflect usage leading up to the last few days. Please check your email for instructions on resetting your password. Araceli G. Campaña, Armando Carlone, Kai Chen, David T. F. Dryden, David A. Leigh, Urszula Lewandowska, Kathleen M. Mullen. 33 publications. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. In contrast, molecular protonated ions of propargyl phenyl ether lose exclusively carbon monoxide. https://doi.org/10.1016/S0166-1280(99)00449-2, https://doi.org/10.1016/S1068-7394(96)80002-9, https://doi.org/10.1016/S0040-4020(01)89259-0. the Altmetric Attention Score and how the score is calculated. The rearranged ions undergo fragmentation, the predominat loss being ethene, and only a small contribution from loss of carbon monoxide is observed. The Journal of Physical Chemistry A 2002, 106 (46) , 11227-11233. Claisen Rearrangement (aromatic) of Aryl Allyl Ether or Allyl Phenyl Ether – In claisen rearrangement allyl phenyl ether is converted into its aromatic enol form by rearrangement. Find more information about Crossref citation counts. Max von Delius, Edzard M. Geertsema, David A. Leigh, and Dan-Tam D. Tang. Richard H. Schlosberg, Paul F. Szajowski, Gerald D. Dupre, Jeffrey A. Danik, Argo Kurs, Terrence R. Ashe, William Im. These metrics are regularly updated to reflect usage leading up to the last few days. Structure-Reactivity Relationships in Homogeneous Gas-Phase Reactions: Thermolyses and Rearrangements. In lieu of an abstract, this is the article's first page. Find more information on the Altmetric Attention Score and how the score is calculated. Wenhua Ou, Sandraliz Espinosa, Héctor J. Meléndez, Silvia M. Farré, Jaime L. Alvarez, Valerie Torres, Ileanne Martínez, Kiara M. Santiago, and Margarita Ortiz-Marciales . Mitteilung). Sergei Zelentsov, Volker Hessel, Elnaz Shahbazali, Timothy Noël. The present work is aimed to develop a me thod for allylation of phenol on Armenian natural zeolites as catalysts. These spectra, together with other evidence of an acid‐induced ortho rearrangement, allow a mechanism to be proposed for the ethene loss. One experiment that it is used for is the Claisen rearrangement . Note: If you do not receive an email within 10 minutes, your email address may not be registered, You have to login with your ACS ID befor you can login with your Mendeley account. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Learn about our remote access options, Royal Society Research Unit, University College of Swansea, Singleton Park, Swansea SA2 8PP, UK, Department of Pharmacology, University of Texas, Health Science Centre, Houston, Texas 77025, USA, Faculté des Sciences, Université de l'Etat à Mons, 19 Avenue Maistriau, Mons 7000, Belgium. A Small Molecule that Walks Non-Directionally Along a Track Without External Intervention. If you have previously obtained access with your personal account, please log in. The Claisen Rearrangement of Phenyl Allyl Ethers, Labeled with Carbon-14. Allylierung von Natriumphenolat mit radioaktivem Allylbromid. Claisen-Umlagerung im Rühr- und Durchflussbetrieb: Verständnis des Mechanismus und Steuerung der Einflussgrößen. Olmstead. THE MECHANISM OF THE PARA-CLAISEN REARRANGEMENT. The first reported Claisen rearrangement is the [3,3]-sigmatropic rearrangement of an allyl phenyl ether to intermediate 1, which quickly tautomerizes to an ortho-substituted phenol. Citations are the number of other articles citing this article, calculated by Crossref and updated daily. The full text of this article hosted at iucr.org is unavailable due to technical difficulties. (Versuche mit14C, 3. -Umlagerung IV. https://doi.org/10.1080/00397911.2019.1695838, https://doi.org/10.1007/978-3-319-45934-9_4, https://doi.org/10.1016/j.tetasy.2015.04.005, https://doi.org/10.1002/9780470638859.conrr144, https://doi.org/10.1002/9780470171875.ch2, https://doi.org/10.1016/0016-2361(83)90308-3, https://doi.org/10.1016/S0069-8040(08)70136-5, https://doi.org/10.1080/15421407108082775, https://doi.org/10.1016/S0065-3160(08)60288-9. Unlimited viewing of the article PDF and any associated supplements and figures. Badhin Gómez,, Pratim K. Chattaraj,, E. Chamorro,, R. Contreras, and. Highly regioselective O-allylation of phenol derivatives using MMZ Collision‐induced dissociation spectra are used to verify the structures of the daughter ions. A Density Functional Study of the Claisen Rearrangement of Allyl Aryl Ether, Allyl Arylamine, Allyl Aryl Thio Ether, and a Series of Meta-Substituted Molecules through Reactivity and Selectivity Profiles. P. Fahrni, W. Haegele, K. Schmid, H. Schmid. -Umlagerung. In lieu of an abstract, this is the article's first page. SAUNDERS, H. J. Find more information on the Altmetric Attention Score and how the score is calculated. The reaction is given below – Claisen rearrangement belongs to ‘sigmatropic rearrangement’ class of reactions.
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